Titanium Boride (TiB2) B2Ti1(l) T(K) Cp S -[G-H(Tr)]/T H-H(Tr) delta-f H delta-f G log Kf 0 100 200 298.15 44.279 56.365 56.365 0. -188.029 -192.185 33.670 300 44.522 56.640 56.366 0.082 -188.036 -192.211 33.467 400 54.890 71.016 58.256 5.104 -188.352 -193.554 25.276 500 61.668 84.036 62.133 10.952 -188.707 -194.814 20.352 600 66.166 95.695 66.773 17.353 -189.094 -196.000 17.063 700 69.496 106.154 71.665 24.142 -189.502 -197.119 14.709 800 72.069 115.603 76.576 31.222 -189.914 -198.179 12.940 900 74.534 124.235 81.399 38.553 -190.337 -199.187 11.560 1000 76.889 132.211 86.086 46.125 -190.811 -200.145 10.455 1100 79.136 139.646 90.621 53.927 -191.383 -201.052 9.547 1200 81.283 146.624 95.000 61.949 -196.034 -201.782 8.783 1300 83.320 153.211 99.227 70.180 -196.067 -202.260 8.127 1400 85.249 159.457 103.308 78.609 -196.075 -202.736 7.564 1500 87.069 165.402 107.251 87.226 -196.077 -203.211 7.076 1600 88.780 171.076 111.064 96.019 -196.091 -203.687 6.650 1700 90.383 176.507 114.755 104.978 -196.137 -204.160 6.273 1800 91.876 181.716 118.331 114.092 -196.236 -204.629 5.938 1900 93.261 186.721 121.800 123.350 -196.409 -205.091 5.638 2000 94.537 191.538 125.167 132.741 -211.366 -205.088 5.356 2100 95.705 196.179 128.439 142.254 -212.502 -204.746 5.093 2100.000 95.705 196.179 128.439 142.254 GLASS <--> LIQUID 2100.000 108.784 196.179 128.439 142.254 TRANSITION 2200 108.784 201.240 131.634 153.132 -212.341 -204.381 4.853 2300 108.784 206.075 134.766 164.011 -212.248 -204.022 4.633 2400 108.784 210.705 137.835 174.889 -312.740 -201.527 4.386 2500 108.784 215.146 140.839 185.768 -312.935 -196.889 4.114 2600 108.784 219.412 143.779 196.646 -313.131 -192.243 3.862 2700 108.784 223.518 146.657 207.524 -313.326 -187.590 3.629 2800 108.784 227.474 149.473 218.403 -313.521 -182.930 3.413 2900 108.784 231.292 152.229 229.281 -313.717 -178.262 3.211 3000 108.784 234.979 154.926 240.160 -313.912 -173.588 3.022 3100 108.784 238.546 157.567 251.038 -314.107 -168.907 2.846 3193.000 108.784 241.762 159.972 261.155 CRYSTAL <--> LIQUID 3200 108.784 242.000 160.151 261.916 314.303 164.220 2.681 3300 108.784 245.348 162.683 272.795 -314.498 -159.527 2.525 3400 108.784 248.595 165.162 283.673 -314.693 -154.828 2.379 3500 108.784 251.749 167.591 294.552 -314.889 -150.124 2.240 3600 108.784 254.813 169.971 305.430 -315.084 -145.413 2.110 3700 108.784 257.794 172.305 316.308 -724.378 -132.909 1.876 3800 108.784 260.695 174.593 327.187 -723.339 -116.937 1.607 3900 108.784 263.521 176.837 338.065 -722.355 -100.992 1.353 4000 108.784 266.275 179.039 348.944 -721.426 -85.072 1.111 4100 108.784 268.961 181.199 359.822 -720.549 -69.174 0.881 4200 108.784 271.582 183.320 370.700 -1679.422 -39.249 0.488 4300 108.784 274.142 185.403 381.579 -1676.470 -0.232 0.003 4400 108.784 276.643 187.448 392.457 -1673.570 38.717 -0.460 4500 108.784 279.088 189.457 403.336 -1670.720 77.600 -0.901 4600 108.784 281.479 191.432 414.214 -1667.918 116.421 -1.322 4700 108.784 283.818 193.373 425.092 -1665.163 155.181 -1.725 4800 108.784 286.108 195.281 435.971 -1662.453 193.883 -2.110 4900 108.784 288.351 197.158 446.849 -1659.788 232.529 -2.479 5000 108.784 290.549 199.004 457.728 -1657.165 271.121 -2.832 5100 108.784 292.703 200.820 468.606 -1654.583 309.661 -3.172 5200 108.784 294.816 202.607 479.484 -1652.041 348.151 -3.497 5300 108.784 296.888 204.367 490.363 -1649.538 386.592 -3.810 5400 108.784 298.921 206.099 501.241 -1647.072 424.986 -4.111 5500 108.784 300.917 207.805 512.120 -1644.642 463.335 -4.400 5600 108.784 302.877 209.485 522.998 -1642.247 501.640 -4.679 5700 108.784 304.803 211.140 533.876 -1639.886 539.903 -4.948 5800 108.784 306.695 212.772 544.755 -1637.558 578.125 -5.207 5900 108.784 308.554 214.379 555.633 -1635.262 616.306 -5.456 6000 108.784 310.383 215.964 566.512 -1632.997 654.449 -5.697