Titanium Boride (TiB2) B2Ti1(cr,l) T(K) Cp S -[G-H(Tr)]/T H-H(Tr) delta-f H delta-f G log Kf 0 0. 0. INFINITE -5.577 -277.811 -277.811 INFINITE 100 7.523 2.518 56.366 -5.385 -278.227 -277.591 144.999 200 28.125 14.046 32.058 -3.602 -279.027 -276.623 72.247 298.15 44.279 28.485 28.485 0. -279.491 -275.334 48.237 300 44.522 28.759 28.486 0.082 -279.498 -275.308 47.935 400 54.890 43.136 30.375 5.104 -279.814 -273.864 35.763 500 61.668 56.156 34.253 10.952 -280.169 -272.336 28.451 600 66.166 67.815 38.893 17.353 -280.556 -270.734 23.569 700 69.496 78.274 43.785 24.142 -280.964 -269.064 20.078 800 72.069 87.723 48.696 31.222 -281.376 -267.336 17.455 900 74.534 96.355 53.519 38.553 -281.799 -265.556 15.412 1000 76.889 104.331 58.206 46.125 -282.273 -263.727 13.776 1100 79.136 111.765 62.741 53.927 -282.845 -261.846 12.434 1200 81.283 118.744 67.120 61.949 -287.496 -259.788 11.308 1300 83.320 125.331 71.347 70.180 -287.529 -257.477 10.346 1400 85.249 131.577 75.428 78.609 -287.537 -255.165 9.520 1500 87.069 137.521 79.371 87.226 -287.539 -252.853 8.805 1600 88.780 143.196 83.184 96.019 -287.553 -250.540 8.179 1700 90.383 148.627 86.875 104.978 -287.599 -248.225 7.627 1800 91.876 153.836 90.451 114.092 -287.698 -245.907 7.136 1900 93.261 158.841 93.920 123.350 -287.872 -243.581 6.696 2000 94.537 163.657 97.287 132.741 -302.828 -240.789 6.289 2100 95.705 168.298 100.558 142.254 -303.964 -237.659 5.911 2200 96.763 172.775 103.740 151.878 -305.057 -234.476 5.567 2300 97.713 177.098 106.836 161.603 -306.118 -231.244 5.252 2400 98.554 181.275 109.851 171.416 -407.675 -225.829 4.915 2500 99.391 185.315 112.789 181.314 -408.851 -218.227 4.560 2600 100.228 189.229 115.654 191.295 -409.944 -210.581 4.231 2700 101.065 193.028 118.450 201.359 -410.953 -202.893 3.925 2800 101.901 196.718 121.180 211.507 -411.879 -195.170 3.641 2900 102.738 200.309 123.847 221.739 -412.721 -187.415 3.376 3000 103.575 203.806 126.454 232.055 -413.479 -179.633 3.128 3100 104.412 207.215 129.004 242.454 -414.153 -171.827 2.895 3193.000 105.190 210.313 131.328 252.201 CRYSTAL <--> LIQUID 3193.000 108.784 241.762 131.328 352.617 TRANSITION 3200 108.784 242.000 131.569 353.378 -314.303 -164.220 2.681 3300 108.784 245.348 134.967 364.257 -314.498 -159.527 2.525 3400 108.784 248.595 138.261 375.135 -314.693 -154.828 2.379 3500 108.784 251.749 141.459 386.014 -314.889 -150.124 2.240 3600 108.784 254.813 144.565 396.892 -315.084 -145.413 2.110 3700 108.784 257.794 147.586 407.770 -724.378 -132.909 1.876 3800 108.784 260.695 150.524 418.649 -723.339 -116.937 1.607 3900 108.784 263.521 153.385 429.527 -722.355 -100.993 1.353 4000 108.784 266.275 156.173 440.406 -721.426 -85.072 1.111 4100 108.784 268.961 158.892 451.284 -720.549 -69.174 0.881 4200 108.784 271.582 161.544 462.162 -1679.422 -39.249 0.488 4300 108.784 274.142 164.133 473.041 -1676.470 -0.232 0.003 4400 108.784 276.643 166.661 483.919 -1673.570 38.717 -0.460 4500 108.784 279.088 169.133 494.798 -1670.720 77.600 -0.901 4600 108.784 281.479 171.549 505.676 -1667.918 116.421 -1.322 4700 108.784 283.818 173.913 516.554 -1665.163 155.181 -1.725 4800 108.784 286.108 176.227 527.433 -1662.453 193.883 -2.110 4900 108.784 288.351 178.492 538.311 -1659.788 232.529 -2.479 5000 108.784 290.549 180.711 549.190 -1657.165 271.121 -2.832 5100 108.784 292.703 182.886 560.068 -1654.583 309.661 -3.172 5200 108.784 294.816 185.018 570.946 -1652.041 348.150 -3.497 5300 108.784 296.888 187.110 581.825 -1649.538 386.592 -3.810 5400 108.784 298.921 189.161 592.703 -1647.072 424.986 -4.111 5500 108.784 300.917 191.175 603.582 -1644.642 463.335 -4.400 5600 108.784 302.877 193.152 614.460 -1642.247 501.640 -4.679 5700 108.784 304.803 195.094 625.338 -1639.886 539.903 -4.948 5800 108.784 306.695 197.002 636.217 -1637.558 578.125 -5.207 5900 108.784 308.554 198.877 647.095 -1635.262 616.306 -5.456 6000 108.784 310.383 200.721 657.974 -1632.997 654.449 -5.697