Titanium Bromide (TiBr4) Br4Ti1(cr) T(K) Cp S -[G-H(Tr)]/T H-H(Tr) delta-f H delta-f G log Kf 0 0. 0. INFINITE -28.556 -592.684 -592.684 INFINITE 100 94.098 120.922 349.954 -22.903 -593.178 -593.675 310.104 200 117.273 194.146 255.191 -12.209 -594.203 -593.819 155.090 298.15 131.503 243.622 243.622 0. -617.977 -590.681 103.485 300 131.815 244.436 243.624 0.244 -618.060 -590.512 102.817 311.400 133.779 249.388 243.745 1.757 CRYSTAL <--> LIQUID 400 133.779 282.886 248.860 13.611 676.266 569.177 74.327 500 133.779 312.738 258.761 26.989 -673.012 -542.785 56.704 600 133.779 337.129 269.852 40.366 -669.899 -517.034 45.012 700 133.779 357.751 280.974 53.744 -666.885 -491.796 36.698 800 133.779 375.615 291.712 67.122 -663.937 -466.985 30.491 900 133.779 391.372 301.927 80.500 -661.078 -442.539 25.684 1000 133.779 405.467 311.589 93.878 -658.370 -418.404 21.855 1100 133.779 418.218 320.712 107.256 -655.873 -394.530 18.735 1200 133.779 429.858 329.329 120.634 -657.574 -370.753 16.138 1300 133.779 440.566 337.480 134.012 -654.777 -346.966 13.941 1400 133.779 450.480 345.202 147.390 -652.077 -323.390 12.066 1500 133.779 459.710 352.531 160.768 -649.487 -300.004 10.447