fH°fG°| Lithium Carbonate (Li2CO3) | C1Li2O3(cr,l) | |||||||||||||
| Enthalpy Reference Temperature = Tr = 298.15 K | Standard State Pressure = p° = 0.1 MPa | |||||||||||||
| J·K-1 mol-1 | kJ·mol-1 | |||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| T/K | Cp° | S° | -[G°-H°(Tr)]/T | H-H°(Tr) | fH° |
fG° |
log Kf | |||||||
| 0 | 0. | 0. | INFINITE | -15.174 | -1207.891 | -1207.891 | INFINITE | |||||||
| 100 | 34.811 | 20.048 | 158.357 | -13.831 | -1211.955 | -1186.400 | 619.712 | |||||||
| 200 | 72.425 | 56.513 | 98.271 | -8.352 | -1214.852 | -1159.562 | 302.847 | |||||||
| 298.15 | 96.232 | 90.171 | 90.171 | 0. | -1216.038 | -1132.120 | 198.343 | |||||||
| 300 | 96.567 | 90.767 | 90.172 | 0.178 | -1216.048 | -1131.600 | 197.029 | |||||||
| 400 | 112.173 | 120.752 | 94.156 | 10.638 | -1216.269 | -1103.403 | 144.090 | |||||||
| 500 | 128.951 | 147.525 | 102.190 | 22.668 | -1222.020 | -1074.589 | 112.262 | |||||||
| 600 | 149.369 | 172.780 | 111.863 | 36.550 | -1220.421 | -1045.224 | 90.995 | |||||||
| 623.150 | 154.643 | 178.533 | 114.233 | 40.069 | I <--> II | |||||||||
| 623.150 | 154.638 | 179.433 | 114.233 | 40.630 | TRANSITION | |||||||||
| 683.150 | 170.212 | 194.286 | 120.612 | 50.331 | II <--> III | |||||||||
| 683.150 | 138.782 | 197.563 | 120.612 | 52.569 | TRANSITION | |||||||||
| 700 | 140.875 | 200.969 | 122.505 | 54.925 | -1214.552 | -1016.396 | 75.844 | |||||||
| 800 | 158.992 | 220.962 | 133.565 | 69.917 | -1212.279 | -988.225 | 64.524 | |||||||
| 900 | 177.025 | 240.727 | 144.376 | 86.716 | -1208.404 | -960.434 | 55.742 | |||||||
| 993.150 | 194.096 | 258.989 | 154.270 | 104.001 | III <--> LIQUID | |||||||||
| 993.150 | 185.435 | 304.066 | 154.270 | 148.770 | TRANSITION | |||||||||
| 1000 | 185.435 | 305.341 | 155.301 | 150.040 | -1158.169 | -933.471 | 48.760 | |||||||
| 1100 | 185.435 | 323.015 | 169.757 | 168.584 | -1152.845 | -911.260 | 43.272 | |||||||
| 1200 | 185.435 | 339.150 | 183.210 | 187.127 | -1147.628 | -889.528 | 38.720 | |||||||
| 1300 | 185.435 | 353.992 | 195.784 | 205.671 | -1142.503 | -868.229 | 34.886 | |||||||
| 1400 | 185.435 | 367.735 | 207.582 | 224.214 | -1137.451 | -847.321 | 31.614 | |||||||
| 1500 | 185.435 | 380.528 | 218.690 | 242.758 | -1132.459 | -826.772 | 28.791 | |||||||
| 1600 | 185.435 | 392.496 | 229.183 | 261.301 | -1127.520 | -806.554 | 26.331 | |||||||
| 1700 | 185.435 | 403.738 | 239.124 | 279.845 | -1413.101 | -772.291 | 23.730 | |||||||
| 1800 | 185.435 | 414.337 | 248.566 | 298.388 | -1406.749 | -734.781 | 21.323 | |||||||
| 1900 | 185.435 | 424.363 | 257.557 | 316.932 | -1400.457 | -697.621 | 19.179 | |||||||
| 2000 | 185.435 | 433.875 | 266.137 | 335.475 | -1394.224 | -660.791 | 17.258 | |||||||
| PREVIOUS: | CURRENT: March 1966 | |||||||||||||
| Lithium Carbonate (Li2CO3) | C1Li2O3(cr,l) | |||||||||||||
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