Phosphoryl Chloride Fluoride (POClF2) | Cl1F2O1P1(g) | |||||||||||||
Enthalpy Reference Temperature = Tr = 298.15 K | Standard State Pressure = p° = 0.1 MPa | |||||||||||||
J·K-1 mol-1 | kJ·mol-1 | |||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
T/K | Cp° | S° | -[G°-H°(Tr)]/T | H-H°(Tr) | fH° | fG° | log Kf | |||||||
0 | 0. | 0. | INFINITE | -14.198 | -961.769 | -961.769 | INFINITE | |||||||
100 | 38.154 | 245.398 | 353.098 | -10.770 | -965.044 | -952.662 | 497.620 | |||||||
200 | 55.039 | 277.016 | 307.567 | -6.110 | -968.551 | -939.053 | 245.256 | |||||||
250 | 62.542 | 290.122 | 302.789 | -3.167 | -969.739 | -931.537 | 194.634 | |||||||
298.15 | 68.838 | 301.689 | 301.689 | 0. | -970.688 | -924.090 | 161.897 | |||||||
300 | 69.062 | 302.116 | 301.691 | 0.128 | -970.721 | -923.801 | 160.848 | |||||||
350 | 74.631 | 313.192 | 302.553 | 3.724 | -972.247 | -915.844 | 136.682 | |||||||
400 | 79.327 | 323.473 | 304.533 | 7.576 | -972.964 | -907.735 | 118.538 | |||||||
450 | 83.259 | 333.051 | 307.176 | 11.644 | -973.527 | -899.546 | 104.417 | |||||||
500 | 86.541 | 341.998 | 310.216 | 15.891 | -973.963 | -891.302 | 93.114 | |||||||
600 | 91.583 | 358.249 | 316.895 | 24.812 | -974.544 | -874.709 | 76.150 | |||||||
700 | 95.154 | 372.650 | 323.851 | 34.159 | -974.844 | -858.043 | 64.028 | |||||||
800 | 97.736 | 385.534 | 330.771 | 43.810 | -974.953 | -841.348 | 54.934 | |||||||
900 | 99.646 | 397.161 | 337.512 | 53.684 | -974.929 | -824.648 | 47.861 | |||||||
1000 | 101.088 | 407.738 | 344.014 | 63.724 | -974.811 | -807.955 | 42.203 | |||||||
1100 | 102.200 | 417.427 | 350.254 | 73.891 | -974.626 | -791.278 | 37.575 | |||||||
1200 | 103.073 | 426.358 | 356.228 | 84.156 | -1037.967 | -773.542 | 33.671 | |||||||
1300 | 103.768 | 434.637 | 361.945 | 94.499 | -1036.928 | -751.548 | 30.198 | |||||||
1400 | 104.331 | 442.348 | 367.416 | 104.905 | -1035.873 | -729.635 | 27.223 | |||||||
1500 | 104.792 | 449.563 | 372.655 | 115.362 | -1034.810 | -707.798 | 24.648 | |||||||
1600 | 105.174 | 456.338 | 377.675 | 125.861 | -1033.744 | -686.032 | 22.397 | |||||||
1700 | 105.495 | 462.725 | 382.492 | 136.395 | -1032.679 | -664.333 | 20.412 | |||||||
1800 | 105.765 | 468.762 | 387.119 | 146.958 | -1031.618 | -642.696 | 18.651 | |||||||
1900 | 105.996 | 474.487 | 391.568 | 157.547 | -1030.564 | -621.118 | 17.076 | |||||||
2000 | 106.194 | 479.929 | 395.851 | 168.157 | -1029.516 | -599.596 | 15.660 | |||||||
2100 | 106.366 | 485.115 | 399.979 | 178.785 | -1028.476 | -578.125 | 14.380 | |||||||
2200 | 106.516 | 490.066 | 403.962 | 189.429 | -1027.441 | -556.704 | 13.218 | |||||||
2300 | 106.646 | 494.804 | 407.810 | 200.087 | -1026.411 | -535.330 | 12.158 | |||||||
2400 | 106.762 | 499.345 | 411.530 | 210.758 | -1025.383 | -514.001 | 11.187 | |||||||
2500 | 106.864 | 503.706 | 415.130 | 221.439 | -1024.357 | -492.714 | 10.295 | |||||||
2600 | 106.955 | 507.899 | 418.618 | 232.130 | -1023.330 | -471.469 | 9.472 | |||||||
2700 | 107.036 | 511.937 | 422.000 | 242.830 | -1022.300 | -450.263 | 8.711 | |||||||
2800 | 107.108 | 515.831 | 425.282 | 253.537 | -1021.264 | -429.095 | 8.005 | |||||||
2900 | 107.174 | 519.591 | 428.469 | 264.251 | -1020.221 | -407.965 | 7.348 | |||||||
3000 | 107.233 | 523.225 | 431.568 | 274.972 | -1019.168 | -386.871 | 6.736 | |||||||
3100 | 107.287 | 526.742 | 434.581 | 285.698 | -1018.103 | -365.811 | 6.164 | |||||||
3200 | 107.335 | 530.149 | 437.515 | 296.429 | -1017.024 | -344.787 | 5.628 | |||||||
3300 | 107.380 | 533.453 | 440.372 | 307.165 | -1015.930 | -323.797 | 5.125 | |||||||
3400 | 107.420 | 536.659 | 443.157 | 317.905 | -1014.817 | -302.839 | 4.653 | |||||||
3500 | 107.458 | 539.773 | 445.874 | 328.649 | -1013.685 | -281.916 | 4.207 | |||||||
3600 | 107.492 | 542.801 | 448.524 | 339.396 | -1012.532 | -261.024 | 3.787 | |||||||
3700 | 107.523 | 545.746 | 451.112 | 350.147 | -1011.357 | -240.165 | 3.391 | |||||||
3800 | 107.552 | 548.614 | 453.640 | 360.901 | -1010.157 | -219.338 | 3.015 | |||||||
3900 | 107.579 | 551.408 | 456.112 | 371.657 | -1008.931 | -198.542 | 2.659 | |||||||
4000 | 107.604 | 554.132 | 458.528 | 382.416 | -1007.679 | -177.779 | 2.322 | |||||||
4100 | 107.627 | 556.790 | 460.893 | 393.178 | -1006.398 | -157.048 | 2.001 | |||||||
4200 | 107.649 | 559.384 | 463.207 | 403.942 | -1005.089 | -136.347 | 1.696 | |||||||
4300 | 107.669 | 561.917 | 465.473 | 414.708 | -1003.750 | -115.679 | 1.405 | |||||||
4400 | 107.688 | 564.392 | 467.693 | 425.476 | -1002.381 | -95.042 | 1.128 | |||||||
4500 | 107.705 | 566.812 | 469.869 | 436.245 | -1000.980 | -74.436 | 0.864 | |||||||
4600 | 107.721 | 569.180 | 472.002 | 447.017 | -999.548 | -53.863 | 0.612 | |||||||
4700 | 107.737 | 571.497 | 474.095 | 457.789 | -998.084 | -33.320 | 0.370 | |||||||
4800 | 107.751 | 573.765 | 476.148 | 468.564 | -996.588 | -12.808 | 0.139 | |||||||
4900 | 107.765 | 575.987 | 478.163 | 479.340 | -995.060 | 7.672 | -0.082 | |||||||
5000 | 107.777 | 578.164 | 480.141 | 490.117 | -993.500 | 28.120 | -0.294 | |||||||
5100 | 107.789 | 580.299 | 482.084 | 500.895 | -991.909 | 48.536 | -0.497 | |||||||
5200 | 107.801 | 582.392 | 483.993 | 511.675 | -990.286 | 68.921 | -0.692 | |||||||
5300 | 107.811 | 584.445 | 485.869 | 522.455 | -988.632 | 89.275 | -0.880 | |||||||
5400 | 107.821 | 586.461 | 487.713 | 533.237 | -986.948 | 109.597 | -1.060 | |||||||
5500 | 107.831 | 588.439 | 489.527 | 544.019 | -985.234 | 129.887 | -1.234 | |||||||
5600 | 107.840 | 590.382 | 491.310 | 554.803 | -983.491 | 150.147 | -1.401 | |||||||
5700 | 107.849 | 592.291 | 493.065 | 565.587 | -981.720 | 170.374 | -1.561 | |||||||
5800 | 107.857 | 594.167 | 494.792 | 576.373 | -979.922 | 190.571 | -1.716 | |||||||
5900 | 107.864 | 596.011 | 496.492 | 587.159 | -978.098 | 210.736 | -1.866 | |||||||
6000 | 107.872 | 597.824 | 498.166 | 597.946 | -976.248 | 230.870 | -2.010 | |||||||
PREVIOUS: March 1963 (1 atm) | CURRENT: March 1963 (1 bar) | |||||||||||||
Phosphoryl Chloride Fluoride (POClF2) | Cl1F2O1P1(g) |
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