Phosphoryl Chloride (OPCl3) | Cl3O1P1(g) | |||||||||||||
Enthalpy Reference Temperature = Tr = 298.15 K | Standard State Pressure = p° = 0.1 MPa | |||||||||||||
J·K-1 mol-1 | kJ·mol-1 | |||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
T/K | Cp° | S° | -[G°-H°(Tr)]/T | H-H°(Tr) | fH° | fG° | log Kf | |||||||
0 | 0. | 0. | INFINITE | -17.880 | -554.226 | -554.226 | INFINITE | |||||||
100 | 50.035 | 251.381 | 392.051 | -14.067 | -557.121 | -543.474 | 283.881 | |||||||
200 | 72.927 | 293.857 | 332.888 | -7.806 | -559.135 | -529.144 | 138.198 | |||||||
250 | 79.947 | 310.927 | 326.826 | -3.975 | -559.553 | -521.594 | 108.981 | |||||||
298.15 | 84.917 | 325.454 | 325.454 | 0. | -559.819 | -514.257 | 90.096 | |||||||
300 | 85.082 | 325.980 | 325.456 | 0.157 | -559.828 | -513.975 | 89.491 | |||||||
350 | 88.953 | 339.399 | 326.507 | 4.512 | -560.724 | -506.246 | 75.553 | |||||||
400 | 91.957 | 351.481 | 328.886 | 9.038 | -560.889 | -498.451 | 65.091 | |||||||
450 | 94.338 | 362.455 | 332.016 | 13.698 | -560.969 | -490.641 | 56.952 | |||||||
500 | 96.257 | 372.497 | 335.569 | 18.464 | -560.982 | -482.825 | 50.440 | |||||||
600 | 99.115 | 390.317 | 343.246 | 28.242 | -560.865 | -467.202 | 40.674 | |||||||
700 | 101.093 | 405.753 | 351.098 | 38.258 | -560.616 | -451.610 | 33.700 | |||||||
800 | 102.506 | 419.349 | 358.797 | 48.442 | -560.283 | -436.060 | 28.472 | |||||||
900 | 103.544 | 431.485 | 366.211 | 58.747 | -559.894 | -420.555 | 24.408 | |||||||
1000 | 104.325 | 442.437 | 373.295 | 69.142 | -559.467 | -405.095 | 21.160 | |||||||
1100 | 104.925 | 452.410 | 380.041 | 79.606 | -559.016 | -389.680 | 18.504 | |||||||
1200 | 105.395 | 461.560 | 386.458 | 90.123 | -622.120 | -373.228 | 16.246 | |||||||
1300 | 105.770 | 470.012 | 392.564 | 100.682 | -620.869 | -352.537 | 14.165 | |||||||
1400 | 106.072 | 477.862 | 398.380 | 111.275 | -619.619 | -331.943 | 12.385 | |||||||
1500 | 106.320 | 485.189 | 403.926 | 121.895 | -618.373 | -311.439 | 10.845 | |||||||
1600 | 106.526 | 492.057 | 409.221 | 132.537 | -617.133 | -291.017 | 9.501 | |||||||
1700 | 106.697 | 498.521 | 414.286 | 143.199 | -615.904 | -270.672 | 8.317 | |||||||
1800 | 106.843 | 504.624 | 419.137 | 153.876 | -614.688 | -250.400 | 7.266 | |||||||
1900 | 106.967 | 510.404 | 423.790 | 164.567 | -613.487 | -230.194 | 6.328 | |||||||
2000 | 107.073 | 515.893 | 428.259 | 175.269 | -612.303 | -210.052 | 5.486 | |||||||
2100 | 107.165 | 521.119 | 432.557 | 185.981 | -611.140 | -189.968 | 4.725 | |||||||
2200 | 107.245 | 526.107 | 436.697 | 196.701 | -610.000 | -169.938 | 4.035 | |||||||
2300 | 107.315 | 530.876 | 440.689 | 207.429 | -608.886 | -149.961 | 3.406 | |||||||
2400 | 107.377 | 535.444 | 444.542 | 218.164 | -607.800 | -130.031 | 2.830 | |||||||
2500 | 107.432 | 539.829 | 448.267 | 228.905 | -606.745 | -110.146 | 2.301 | |||||||
2600 | 107.481 | 544.043 | 451.870 | 239.650 | -605.723 | -90.302 | 1.814 | |||||||
2700 | 107.524 | 548.100 | 455.359 | 250.400 | -604.736 | -70.497 | 1.364 | |||||||
2800 | 107.563 | 552.011 | 458.742 | 261.155 | -603.784 | -50.728 | 0.946 | |||||||
2900 | 107.598 | 555.787 | 462.023 | 271.913 | -602.869 | -30.992 | 0.558 | |||||||
3000 | 107.630 | 559.435 | 465.210 | 282.674 | -601.992 | -11.287 | 0.197 | |||||||
3100 | 107.658 | 562.965 | 468.307 | 293.439 | -601.151 | 8.389 | -0.141 | |||||||
3200 | 107.685 | 566.383 | 471.319 | 304.206 | -600.346 | 28.038 | -0.458 | |||||||
3300 | 107.708 | 569.697 | 474.250 | 314.976 | -599.576 | 47.663 | -0.754 | |||||||
3400 | 107.730 | 572.913 | 477.105 | 325.748 | -598.838 | 67.266 | -1.033 | |||||||
3500 | 107.750 | 576.036 | 479.887 | 336.522 | -598.130 | 86.846 | -1.296 | |||||||
3600 | 107.768 | 579.071 | 482.600 | 347.298 | -597.449 | 106.408 | -1.544 | |||||||
3700 | 107.785 | 582.024 | 485.247 | 358.075 | -596.791 | 125.950 | -1.778 | |||||||
3800 | 107.801 | 584.899 | 487.832 | 368.855 | -596.154 | 145.475 | -2.000 | |||||||
3900 | 107.815 | 587.699 | 490.357 | 379.635 | -595.533 | 164.984 | -2.210 | |||||||
4000 | 107.829 | 590.429 | 492.825 | 390.418 | -594.925 | 184.476 | -2.409 | |||||||
4100 | 107.841 | 593.092 | 495.238 | 401.201 | -594.325 | 203.954 | -2.598 | |||||||
4200 | 107.852 | 595.691 | 497.599 | 411.986 | -593.730 | 223.417 | -2.779 | |||||||
4300 | 107.863 | 598.229 | 499.910 | 422.772 | -593.135 | 242.866 | -2.950 | |||||||
4400 | 107.873 | 600.709 | 502.173 | 433.558 | -592.538 | 262.301 | -3.114 | |||||||
4500 | 107.883 | 603.133 | 504.389 | 444.346 | -591.933 | 281.722 | -3.270 | |||||||
4600 | 107.891 | 605.504 | 506.562 | 455.135 | -591.317 | 301.130 | -3.419 | |||||||
4700 | 107.900 | 607.825 | 508.692 | 465.924 | -590.688 | 320.524 | -3.562 | |||||||
4800 | 107.907 | 610.096 | 510.781 | 476.715 | -590.042 | 339.905 | -3.699 | |||||||
4900 | 107.915 | 612.321 | 512.830 | 487.506 | -589.376 | 359.272 | -3.830 | |||||||
5000 | 107.921 | 614.502 | 514.842 | 498.298 | -588.689 | 378.625 | -3.955 | |||||||
5100 | 107.928 | 616.639 | 516.817 | 509.090 | -587.977 | 397.965 | -4.076 | |||||||
5200 | 107.934 | 618.735 | 518.757 | 519.883 | -587.238 | 417.289 | -4.192 | |||||||
5300 | 107.940 | 620.791 | 520.663 | 530.677 | -586.471 | 436.600 | -4.303 | |||||||
5400 | 107.945 | 622.808 | 522.536 | 541.471 | -585.675 | 455.896 | -4.410 | |||||||
5500 | 107.950 | 624.789 | 524.377 | 552.266 | -584.849 | 475.176 | -4.513 | |||||||
5600 | 107.955 | 626.734 | 526.188 | 563.061 | -583.990 | 494.442 | -4.612 | |||||||
5700 | 107.959 | 628.645 | 527.968 | 573.857 | -583.100 | 513.692 | -4.707 | |||||||
5800 | 107.964 | 630.523 | 529.720 | 584.653 | -582.177 | 532.926 | -4.800 | |||||||
5900 | 107.968 | 632.368 | 531.445 | 595.450 | -581.220 | 552.143 | -4.888 | |||||||
6000 | 107.972 | 634.183 | 533.142 | 606.247 | -580.231 | 571.344 | -4.974 | |||||||
PREVIOUS: June 1962 (1 atm) | CURRENT: June 1962 (1 bar) | |||||||||||||
Phosphoryl Chloride (OPCl3) | Cl3O1P1(g) |
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